Document Type

Article

Publication Date

8-9-2019

DOI

10.1021/acsomega.9b00765

Publication Title

ACS Omega

First Page

13034

Last Page

13041

Volume

4

Issue

8

College/School

Case School of Engineering

Department/Center

Chemical & Biomolecular Engineering

Abstract

Active colloidal particles regularly interact with surfaces in applications ranging from microfluidics to sensing. Recent work has revealed the complex nature of these surface interactions for active particles. Herein, we summarize experiments and simulations that show the impact of charged nanoparticles on the propulsion of an active colloid near a boundary. Adding charged nanoparticles not only decreased the average separation distance of a passive colloid because of depletion attraction as expected but also decreased the apparent propulsion of a Janus colloid to near zero. Complementary agent-based simulations considering the impact of hydrodynamics for active Janus colloids were conducted in the range of separation distances inferred from experiment. These simulations showed that propulsion speed decreased monotonically with decreasing average separation distance. Although the trend found in experiments and simulations was in qualitative agreement, there was still a significant difference in the magnitude of speed reduction. The quantitative difference was attributed to the influence of charged nanoparticles on the conductivity of the active particle suspension. Follow-up experiments delineating the impact of depletion and conductivity showed that both contribute to the reduction of speed for an active Janus particle. The experimental and simulated data suggests that it is necessary to consider the synergistic effects between various mechanisms influencing interactions experienced by an active particle near a boundary.

Rights

This is an open access article published under an ACS AuthorChoice License, which permits copying and redistribution of the article or any adaptations for non-commercial purposes: https://pubs.acs.org/page/policy/authorchoice_termsofuse.html

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