Document Type
Article
Publication Date
2005
Abstract
We report on the synthesis of new quadripolar triarylmethyl cations related to Crystal Violet and the characterization of their NLO properties by a new hyper Rayleigh scattering (HRS) technique. We have prepared a range of triarylmethyl cations that incorporate one, two or three naphthyl moieties. These structural modifications have a direct influence on the NLO properties that have been determined by the Timed-Correlated Single Photon Counting 45° HRS (TCSP-45-HRS) and also influence absorption properties as seen in the UV-Visible spectra.
Keywords
absorption, characterization, dyes, nonlinear optics, synthesis (chemical), ultraviolet spectroscopy, hyper-Rayleigh scattering (HRS), NLO properties, triarylmethyl cations, positive ions, Rayleigh scattering
Publication Title
Nonlinear Optics Quantum Optics
Rights
© 2005 Old City Publishing, Inc. Request granted provided that "full credit to the original publication is given" and the publication is more than 12 months past original publication date
Recommended Citation
Mao, Guilin; Wiggers, Greg A.; Petschek, Rolfe G.; and Singer, Kenneth D., "Synthesis and MRS NLO Characterization of New Triarylmethyl Cations" (2005). Faculty Scholarship. 441.
https://commons.case.edu/facultyworks/441